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Decontaminating effluent water containing non-ferrous heavy elements and radionuclides on titanium phosphate

 

Author: Gerasimova L. G., Maslova M. V., Nikolaev A. I.

Reference: Gazette “ЦВЕТНЫЕ МЕТАЛЛЫ“, 2011

ISSN: 0372-2929

DOI:

Keywords: Sorption, desorption, composite sorbents, flow sheet, wastewater, non-ferrous metal cations, radioactive isotopes

Abstract: A method for the production of a new, composite inorganic adsorbent based on titanium phosphate derived from current wastes of apatite-nepheline ore processing is described. The new variant of waste recovery makes it possible to implement advanced and environmentally friendly patterns. In this work, a scientific justification for parameters of titanium phosphate precursor synthesis and treatment is proposed. The technology is highly effective; the adsorbent can be used in cleaning of weak-salt aqueous effluents. The chemical stability of the composite adsorbent in various solutions has been studied to determine the optimal operating conditions for it. It has been found that after five sorption desorption cycles the material’s ion-exchanges capacity remains practically unchanged. The possibility of recovering the sorbent saturated with transition metals has been examined by using different mineral acids. Methods for the spent material utilization in the production of building fillers are discussed. The paper provides the data on purification of real wastewater of multimineral ore processing. It was noted that the cations of water hardness are first absorbed by the material, later becoming displaced by elements forming stronger bonds with phosphate groups. By the example of artificial radioactive solutions containing 137Cs, 152Eu, 234Th, 238U, 60Со, we determined the material’s ion-exchange capacity and its dependence on the adsorbent’s initial bulk density and number of sorption stages. The material has demonstrated superior ion-exchange properties in wastewater purification from non-ferrous metals and radionuclides.

URL: http://www.rudmet.ru/journal/656/article/8383/

Radionuclides in ground waters from observation holes in the Shelter local area (probably English)

Author: Odintsov, A. A.; Khan, V. E.; Krasnov, V. A.; Pazukhin, E. M.

Reference: Gazette “Radiochemistry”, 2007

ISSN: 0033-8311

DOI: 621.039.542

Keywords: drinking water, contamination, water pollution, radioisotopes, ricer, lake

Abstract: The volume activity of 3H, 90Sr, 137Cs, 234U, 235U, 238U, 238Pu, 239+240Pu, and 241Am in ground waters from observation holes 1-G-6-G in the north section of the Shelter local area of the Chernobyl Nuclear Power Plant (CNPP) was measured. The distribution of radionuclides in the suspension fractions of the ground waters was evaluated. The main contribution to the pollution of ground waters with uranium is due to natural uranium isotopes: 234,235,238U. The activity ratios of 238Pu, 239+240Pu, and 241Am in ground waters are similar to those in the spent fuel of 4th CNPP block.

URL: http://connection.ebscohost.com/c/articles/27081216/radionuclides-ground-waters-from-observation-holes-shelter-local-area

Radionuclides and microelements in natural waters in the zone of a uranium-vanadium deposit (Republic of Karelia) (English)

 

Author: Lukin A.A., Mel’nik N.A.

Reference: Gazette “Water Resources”, 2006

ISSN: 0097-8087

DOI: 10.1134/S009780780601009X

Keywords: radionuclides, water, soil, fish, concentration of uranium and vanadium

Abstract: The results of studies performed in the area of a uranium-vanadium deposit are used to characterize the concentration and distribution of microelements and radionuclides in water, soil, and fish. The exposure rate on the surface of the examined samples is found to be equal to 15�20 �r/h, i.e., to lie at the background level, which means that these samples are not an external radiation hazard for population. Concentrations of U and V in water somewhat greater than background values were recorded, though they are lower than MAC for fishery water bodies. The collected data show that a delicate equilibrium has formed in this territory, although the hydrochemical characteristics have not changed within the recent 40 years, and radionuclide content of water, soil, bottom sediments, and fish are at an extremely low level.

 

URL: http://direct.bl.uk/bld/PlaceOrder.do?UIN=183368045&ETOC=RN&from=searchengine

Radionuclides in groundwater fields “Karazhyra” (Kazakhstan)

Author: Klimova E.V.

Reference: Gazette “ЭКОЛОГИЧЕСКАЯ БЕЗОПАСНОСТЬ В АПК.” (Ecological safety in agricultural sector), Moscow, 2003

ISSN: 1726-2211

DOI:

Keywords: groundwater, radionuclides, contamination of water, Kazakhstan

Abstract:

URL: http://elibrary.ru/item.asp?id=6576226

Radionuclides and heavy metals in groundwater of coal field “Karazhyra” (East Kazakhstan)

Author: Artamonova E.N.

Reference: Altai State University, 2004

ISSN:

Keywords: groundwater, coal field, radionuclides, migration, ecology

Abstract: Describes the migration of both natural and anthropogenic radionuclides, as well as heavy metals, in groundwater. 

URL: http://www.dissercat.com/content/radionuklidy-i-tyazhelye-metally-v-podzemnykh-vodakh-ugolnogo-mestorozhdeniya-karazhyra-vost

Effect of multiple irrigation with water, containing radionuclides, accumulating in different organs of agricultural plants (tomato)

 

Author: Mel’chenko A.I., Zhivchikov V.G., Mel’chenko E.A.

Reference: Gazette “ТРУДЫ КУБАНСКОГО ГОСУДАРСТВЕННОГО АГРАРНОГО УНИВЕРСИТЕТА“ (Proceedings of Kuban State Agrarian University), 2011

ISSN: 1999-1703

Keywords: accumulation, radionuclides, tomato

Abstract: Describes various conditions of accumulation of radionuclides in agricultural products, according to diverse ways of irrigation with water. Experiments on tomato. 

URL: http://elibrary.ru/item.asp?id=17286438

Lake fish as the main contributor of internal dose to lakeshore residents in the Chernobyl contaminated area

Title: Lake fish as the main contributor of internal dose to lakeshore residents in the Chernobyl contaminated area

Author: I.G Travnikova, A.N Bazjukin, G.Ja Bruk, V.N Shutov, M.I Balonov, L Skuterud, H Mehli, P Strand

Reference: Journal of Environmental Radioactivity, Volume 77, Issue 1, 2004, Pages 63-75

DOI: http://dx.doi.org/10.1016/j.jenvrad.2004.03.003

Keywords: Chernobyl; 137Cs; Lake; Internal exposure

Abstract: Two field expeditions in 1996 studied 137Cs intake patterns and its content in the bodies of adult residents from the village Kozhany in the Bryansk region, Russia, located on the shore of a drainless peat lake in an area subjected to significant radioactive contamination after the 1986 Chernobyl accident. The 137Cs contents in lake water and fish were two orders of magnitude greater than in local rivers and flow-through lakes, 10 years after Chernobyl radioactive contamination, and remain stable. The 137Cs content in lake fish and a mixture of forest mushrooms was between approximately 10–20 kBq/kg, which exceeded the temporary Russian permissible levels for these products by a factor of 20–40. Consumption of lake fish gave the main contribution to internal doses (40–50%) for Kozhany village inhabitants Simple countermeasures, such as Prussian blue doses for dairy cows and pre-boiling mushrooms and fish before cooking, halved the 137Cs internal dose to inhabitants, even 10 years after the radioactive fallout.

URL: http://www.sciencedirect.com/science/article/pii/S0265931X04000761

Decision making framework for application of forest countermeasures in the long term after the Chernobyl accident

Title: Decision making framework for application of forest countermeasures in the long term after the Chernobyl accident

Author: S.V. Fesenko, G. Voigt, S.I. Spiridonov, I.A. Gontarenko

Reference: Journal of Environmental Radioactivity, Volume 82, Issue 2, 2005, Pages 143-166

DOI: http://dx.doi.org/10.1016/j.jenvrad.2004.10.014

Keywords: Chernobyl accident; Forest countermeasures; 137Cs; Decision making

Abstract: After the ChNPP accident a very large part of the territories covered by natural and artificial forests are contaminated with long-lived radionuclides, especially 137Cs. To protect people against exposure associated with forest contamination in the most affected regions of the NIS countries, countermeasures have been developed and recommended for the forest management. The paper presents a decision making framework to optimise forest countermeasures in the long term after the ChNPP accident. The approach presented is based on the analysis of the main exposure pathways and application of radiological, socio-economical and ecological criteria for the selection of optimal countermeasures strategies. Because of the diversity of these criteria modern decision support technologies based on multi-attributive analysis were applied. The results of the application of this approach are presented in a selected study area (Novozybkov district, Bryansk region, Russian Federation). The results prove and emphasize the need for a flexible technique to provide the optimised forest countermeasures taking into account radioecological, social and economic features of contaminated forests.

URL: http://www.sciencedirect.com/science/article/pii/S0265931X05000378

Model-directed sampling in Chernobyl forests: general methodology and 1994 sampling program

Title: Model-directed sampling in Chernobyl forests: general methodology and 1994 sampling program

Author: W.R. Schell, I. Linkov, V. Rimkevich, O. Chistic, A. Lutsko, A.M. Dvornik, T.A. Zhuchenko

Reference: Science of The Total Environment, Volume 180, Issue 3, 23 February 1996, Pages 229-240

DOI: http://dx.doi.org/10.1016/0048-9697(95)04946-0

Keywords: Chernobyl; Forest; Radionuclide contamination; Forest ecosystem modeling; Forest sampling

Abstract: Radiologically-contaminated forest and natural ecosystems contribute significantly to the human radiation dose in the intermediate (several years) and long (several decades) terms following the radionuclide release. As a result of the Chernobyl nuclear power plant accident in 1986, extensive forested areas in Europe were significantly contaminated with cesium, strontium, plutonium and other radionuclides. This study develops a dynamic model that describes the pathways of radionuclides which undergo complex transfer processes in forests and natural ecosystems. This generic model, FORESTRATH, calculates time-dependent radionuclide concentrations in forest compartments based on the information available on residence half-times. Because of the high complexity, traditional sampling programs often provide only limited and fragmented information for the ecosystem to be modeled. A model-directed sampling program was initiated which implies close feedback between ecosystem sampling and modeling of the radionuclide pathways using the FORESTPATH model. This program is now being applied by an international team of USA, European Union (EU) and Newly Independent States (NIS) members in the Chernobyl Nuclear Power Plant (NPP) Exclusion Zone.

URL: http://www.sciencedirect.com/science/article/pii/0048969795049460

Application of potassium chloride to a Chernobyl-contaminated lake: modelling the dynamics of radiocaesium in an aquatic ecosystem and decontamination of fish

Title: Application of potassium chloride to a Chernobyl-contaminated lake: modelling the dynamics of radiocaesium in an aquatic ecosystem and decontamination of fish

Author: James T Smith, Anatoly V Kudelsky, Igor N Ryabov, Rolf H Hadderingh, Anatoly A Bulgakov

Reference: Science of The Total Environment, Volume 305, Issues 1–3, 15 April 2003, Pages 217-227

DOI: http://dx.doi.org/10.1016/S0048-9697(02)00477-1

Keywords: Chernobyl; Fish; Radiocaesium; Countermeasures

Abstract: This study tests a whole-lake experiment to reduce the bioaccumulation of radiocaesium (137Cs) in fish in lakes contaminated by the Chernobyl accident. In many lakes in the Chernobyl contaminated areas, radiocaesium activity concentrations in fish are still significantly higher (up to 100 times in some species) than acceptable limits for human consumption. Estimates of the long-term rate of decline of 137Cs in fish in these regions, in the absence of countermeasures, show that radioactivity in fish in some lakes may remain above acceptable consumption limits for a further 50–100 years from the present date. In February 1998 we applied 15 t of potassium chloride to Lake Svyatoe, Kostiukovichy. The addition of potassium chloride fertilizer to the lake resulted in a decrease in activity concentration of 137Cs to approximately 40% of pre-countermeasure values in a number of different fish species. In contrast to Lake Svyatoe, 137Cs activity concentrations in fish from four control lakes showed no systematic decrease over the study period. Simplified models for transfers of 137Cs in lakes successfully ‘blind’ predicted the changes in 137Cs in water and fish resulting from this major alteration of the potassium concentration of the lake. The experiment represents the first test of a predictive model for the dynamics of radiocaesium in response to a major perturbation in potassium (its major competitor ion) in a whole lake ecosystem.

URL: http://www.sciencedirect.com/science/article/pii/S0048969702004771

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